Boiler Blowdown pH Neutralization System
There are two main groups of Chemicals for Boilers to choose from. One chemical group for boilers is for steam boilers and the second is for hot water boilers. Steam Boiler Chemicals - These include Oxygen Scavengers, Amines, Phosphates, Polymers, and Alkalinity Builders. Oxygen Scavengers - Most common type is 38%, pH < 4. Other solutions come blended with a cobalt catalyst and alkalinity contributors.
with pH adjustment chemicals, amines, and oxygen control chemicals, called scavengers. The condensate system is treated with pH adjustment and corrosion control chemicals, volatile amines and filming amines. The boiler is treated with chemicals to control deposition of salts and corrosion products, buffering of pH, and dispersants.
A common recommendation is to maintain boiler water at 8.5 pH. Acidic water is corrosive. Alkalinic water is more prone to scaling. Alkalinity is a measure of the bicarbonate (HCO3), carbonate (CO3) and hydroxyl (OH) ions in the water. pH and alkalinity ratings are NOT the same and are NOT proportional. pH is rated on the Scale and alkalinity is measured in parts per million (ppm).
The result is continuously changing chemistry and increasing pH of a body of water that is already quite alkaline. To maintain an effective chemistry boilers periodically blowdown a small volume of water that will be high in TDS and possibly TSS as well.
• The pH of the feed water should be below 9.2, to prevent copper loss in the system • Optimum pH in the feed water should be 8.5-9.2 Deaerator Ratings • Deaerators are categorized by the quantity of oxygen that they are able to remove at boiling point. The categories are; –Preheat Boiler Feed (Atmospheric Feed Water …
In high-purity systems, raw water in-leakage (e.g., condenser leakage) lowers boiler water pH when magnesium hydroxide precipitates, resulting in corrosion, formation of atomic hydrogen, and initiation of hydrogen attack. Coordinated phosphate/pH control can be used to minimize the decrease in boiler water pH that results from condenser leakage.
pH Treatment | CleanBoiler.org